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Dr. Chavez was Walter White's psychiatrist.
Walt was referred to Dr. Chavez by Dr. Delcavoli and Dr. Soper after Walt was found naked in a supermarket. Chavez pressed upon Walt the need to ascertain that his "fugue state" will not happen again before he is safe to be released from medical care. Walt asked about doctor-patient confidentiality and after Chavez told him that he couldn't share anything with Walt's family or anyone else, Walt confessed that he had invented the fugue state ("Bit by a Dead Bee").